Atomic Structure and Periodicity

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Edition: 1st
Format: Paperback
Pub. Date: 2003-01-02
Publisher(s): Wiley-RSC
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Summary

Atomic Structure and Periodicity presents basic atomic theory as given in first and second year courses at university. It demonstrates that the structure of the Periodic Table as we know it is based on sound principles. Throughout the book, theoretical concepts are presented, along with the experimental evidence for them. Foundations are laid in the introductory chapter, which deals with fundamental particles, electromagnetic radiation and Heisenberg's uncertainty principle. Atomic orbitals are then described, using a minimum of mathematics, followed by a discussion of the electron configurations of the elements. Further chapters reveal the relationships between the electronic configurations of the elements and some properties of their atoms; and the variations in the properties of their fluorides and oxides across the periods and down the groups of the Periodic Table.

Table of Contents

Atomic Particles, Photons and the Quantization of Electron Energies; Heisenberg's Uncertainty Principle
1(21)
Fundamental Particles
1(4)
Electromagnetic Radiation
5(3)
The Photoelectric Effect
8(3)
Wave--Particle Duality
11(2)
The Bohr Frequency Condition
13(1)
The Hydrogen Atom
14(3)
The Observation of Electrons; the Heisenberg Uncertainty Principle
17(4)
Atomic Orbitals
21(14)
The Hydrogen Atom
21(14)
The Electronic Configurations of Atoms; the Periodic Classification of the Elements
35(24)
Polyelectronic Atoms
36(6)
The Electronic Configurations and Periodic Classification of the Elements
42(8)
The Electronic Configurations of Elements Beyond Neon
50(6)
The Periodic Table Summarized
56(3)
Periodicity I: Some Atomic Properties; Relativistic Effects
59(40)
Periodicity of Ionization Energies
59(11)
Variations in Electron Attachment Energies
70(4)
Variations in Atomic Size
74(11)
Electronegativity
85(6)
Relativistic Effects
91(8)
Periodicity II: Valencies and Oxidation States
99(28)
An Overview of Chemical Bonding
99(10)
Valency and Oxidation State: Differences of Terminology
109(2)
Valency and the Octet and 18-Electron Rules
111(6)
Periodicity of Valency and Oxidation States in the s- and p-Block Elements
117(3)
Oxidation States of the Transition Elements
120(3)
Oxidation States of the f-Block Elements
123(4)
Periodicity III: Standard Enthalpies of Atomization of the Elements
127(15)
Periodicity of the Standard Enthalpies of Atomization of the Elements
127(15)
Periodicity IV: Fluorides and Oxides
142(26)
The Fluorides and Oxides of the Elements
142(1)
Fluorides of the Elements
143(9)
Oxides of the Elements
152(16)
Answers to Problems 168(9)
Subject Index 177

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