Chemical Thermodynamics at a Glance
by Jenkins, H. Donald BrookeBuy New
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Summary
Author Biography
Table of Contents
| Preface | |
| Symbols And Notation | |
| Thermodynamic Changes, Properties & Types Of Function | |
| Intensive / Extensive Properties, History | |
| Independent Functions & State Functions | |
| Integration in Thermodynamics | |
| Graphical Gradients & Intercepts Differentiation in Thermodynamics | |
| Equation of State for An Ideal Gas | |
| The Ideal Gas | |
| Partial Derivatives ( <$$$>Z/ <$$$>Y)Z Simplified | |
| Rearrangement of Equations | |
| Logarithms & Exponentials | |
| Adapting Equations In Thermodynamics To Apply To Special Conditions | |
| Thermodynamics: Main Features | |
| Definitions | |
| Sign Conventions | |
| Heat & Work | |
| Zeroth Law of Thermodynamics | |
| Spontaneous Processes | |
| Heat & Work | |
| First Law of Thermodynamics | |
| Work of Expansion | |
| Irreversible & Reversible Changes | |
| Internal Energy, U And Enthalpy, H; Qp & Qv And Heat Capacities, Cp & Cv | |
| Reference States | |
| Thermodynamic Data at 298 K And At Other Temperatures | |
| Bond Enthalpy (Energy) | |
| Spontaneity, Entropy & Gibbs Energy | |
| Entropy & Second Law | |
| The Equivalence of The Criteria, <$$$>G System 0 To Judge The Spontaneity of Processes | |
| Calculation of Entropy | |
| The Third Law of Thermodynamics | |
| Absolute (Third Law) Entropy, So | |
| The Statistical Definition of Entropy | |
| The Boltzman Equation: S = k ln W | |
| Qualitative Application of Theory General Variation Of Gibbs Energy Function, G With Temperature, T At Constant Pressure (Dp = 0) For Any Phase of A Pure Substance | |
| Qualitative Application of Theory General Variation of Enthalpy and Entropy Functions, H and S, With Temperature, T at Constant Pressure (Dp = 0) For any Phase of A Pure Substance | |
| Qualitative Application of Theory So Far | |
| Variation Of Gibbs Energy, G With Pressure, P at Constant Temperature (Dt = 0) and Variation of Entropy, S with Pressure, P at Constant Temperature (Dt= 0) For an Ideal Gas | |
| Qualitative Application of Theory:General Variation of Gibbs Energy Function, G Versus Temperature, T For Solid, Liquid And Gaseous Phases | |
| Prediction of Properties | |
| Qualitative Application of Theory | |
| General Variation of Enthalpy Function, H With Temperature, T for Solid, Liquid and Gaseous Phases | |
| Qualitative Application of Theory:Effect of Pressure on Melting Point, Tm and Boiling Point, Tb | |
| Case (i): (Normal) Substances for Which:Vg Vl Vs | |
| Qualitative Application Of Theory:Effect Of Pressure On Melting Point, Tm And Boiling Point, Tb | |
| Case (ii): Water for which Vg Vl | |
| Quantitative Applicatons:Approach to Phase Equilibria | |
| The Clapeyron Equation | |
| Applications:Quantitative Approach to Phase Equilibria | |
| The Clausius -Clapeyron Equation | |
| Measurement of Vapour Pressure Over A Liquid, and Determination Of <$$$>Vapho for A Liquid | |
| Trouton's Rule | |
| Applications | |
| Open Systems | |
| Chemical Potential | |
| Chemical Reactions | |
| Applications: Coupled Reactions | |
| Chemical Potentials Applied to Physical Processes | |
| Closed & Open Systems | |
| The Phase Rule | |
| Quantitative Thermodynamics of Phases in Equilibrium | |
| Ideal & Real Gases | |
| Dalton's Law of Partial Pressures | |
| Quantitative Thermodynamics of Phases in Equilibrium | |
| Ideal Liquid Mixtures | |
| Vapour Pressure & Raoult's Law | |
| Quantitative Thermodynamics of Phases in Equilibrium | |
| Ideal Liquid Mixtures | |
| Real Liquid Mixtures | |
| Quantitative Thermodynamics of Phases in Equilibrium | |
| Binary Liquid Mixtures | |
| Quantitative Thermodynamics of Phases in Equilibrium | |
| General Use Of Chemical Potentials To Establish Equilibrium Thermodynamic Relationships | |
| QUantitative Thermodynamics of Phases in Equilibrium | |
| Interpretation of The Nature of The Logarithmic Term | |
| Molality | |
| Table of Contents provided by Publisher. All Rights Reserved. |
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