Chemical Thermodynamics at a Glance

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Edition: 1st
Format: Paperback
Pub. Date: 2007-12-26
Publisher(s): Wiley-Blackwell
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Summary

Chemical thermodynamics considers the energy transformations which drive or which occur as a result of chemical reactions. It is a central discipline of chemistry and chemical engineering, allowing prediction of the direction of spontaneous chemical change and the position of chemical equilibrium in any reacting system. Being grounded in maths, it is often perceived as a difficult subject and many students are never fully comfortable with it. Chemical Thermodynamics at a Glance provides a concise overview of the main principles of Chemical Thermodynamics for students studying chemistry and related courses at undergraduate level. Based on the highly successful and student friendly "at a Glance" approach, the information is presented in integrated, self contained double page spreads of text and illustrative material. The material developed in this book has been chosen to ensure the student grasps the essence of thermodynamics, so those wanting an accessible overview will find this book an ideal source of the information they require. In addition, the structured presentation will provide an invaluable aid to revision for students preparing for examinations.

Author Biography

Professor H.D.B. Jenkins is based in the Department of Chemistry, University of Warwick, Coventry, UK

Table of Contents

Preface
Symbols And Notation
Thermodynamic Changes, Properties & Types Of Function
Intensive / Extensive Properties, History
Independent Functions & State Functions
Integration in Thermodynamics
Graphical Gradients & Intercepts Differentiation in Thermodynamics
Equation of State for An Ideal Gas
The Ideal Gas
Partial Derivatives ( <$$$>Z/ <$$$>Y)Z Simplified
Rearrangement of Equations
Logarithms & Exponentials
Adapting Equations In Thermodynamics To Apply To Special Conditions
Thermodynamics: Main Features
Definitions
Sign Conventions
Heat & Work
Zeroth Law of Thermodynamics
Spontaneous Processes
Heat & Work
First Law of Thermodynamics
Work of Expansion
Irreversible & Reversible Changes
Internal Energy, U And Enthalpy, H; Qp & Qv And Heat Capacities, Cp & Cv
Reference States
Thermodynamic Data at 298 K And At Other Temperatures
Bond Enthalpy (Energy)
Spontaneity, Entropy & Gibbs Energy
Entropy & Second Law
The Equivalence of The Criteria, <$$$>G System 0 To Judge The Spontaneity of Processes
Calculation of Entropy
The Third Law of Thermodynamics
Absolute (Third Law) Entropy, So
The Statistical Definition of Entropy
The Boltzman Equation: S = k ln W
Qualitative Application of Theory General Variation Of Gibbs Energy Function, G With Temperature, T At Constant Pressure (Dp = 0) For Any Phase of A Pure Substance
Qualitative Application of Theory General Variation of Enthalpy and Entropy Functions, H and S, With Temperature, T at Constant Pressure (Dp = 0) For any Phase of A Pure Substance
Qualitative Application of Theory So Far
Variation Of Gibbs Energy, G With Pressure, P at Constant Temperature (Dt = 0) and Variation of Entropy, S with Pressure, P at Constant Temperature (Dt= 0) For an Ideal Gas
Qualitative Application of Theory:General Variation of Gibbs Energy Function, G Versus Temperature, T For Solid, Liquid And Gaseous Phases
Prediction of Properties
Qualitative Application of Theory
General Variation of Enthalpy Function, H With Temperature, T for Solid, Liquid and Gaseous Phases
Qualitative Application of Theory:Effect of Pressure on Melting Point, Tm and Boiling Point, Tb
Case (i): (Normal) Substances for Which:Vg Vl Vs
Qualitative Application Of Theory:Effect Of Pressure On Melting Point, Tm And Boiling Point, Tb
Case (ii): Water for which Vg Vl
Quantitative Applicatons:Approach to Phase Equilibria
The Clapeyron Equation
Applications:Quantitative Approach to Phase Equilibria
The Clausius -Clapeyron Equation
Measurement of Vapour Pressure Over A Liquid, and Determination Of <$$$>Vapho for A Liquid
Trouton's Rule
Applications
Open Systems
Chemical Potential
Chemical Reactions
Applications: Coupled Reactions
Chemical Potentials Applied to Physical Processes
Closed & Open Systems
The Phase Rule
Quantitative Thermodynamics of Phases in Equilibrium
Ideal & Real Gases
Dalton's Law of Partial Pressures
Quantitative Thermodynamics of Phases in Equilibrium
Ideal Liquid Mixtures
Vapour Pressure & Raoult's Law
Quantitative Thermodynamics of Phases in Equilibrium
Ideal Liquid Mixtures
Real Liquid Mixtures
Quantitative Thermodynamics of Phases in Equilibrium
Binary Liquid Mixtures
Quantitative Thermodynamics of Phases in Equilibrium
General Use Of Chemical Potentials To Establish Equilibrium Thermodynamic Relationships
QUantitative Thermodynamics of Phases in Equilibrium
Interpretation of The Nature of The Logarithmic Term
Molality
Table of Contents provided by Publisher. All Rights Reserved.

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