Combustion : Physical and Chemical Fundamentals, Modelling and Simulation, Experiments, Pollutant Formation

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Edition: 2nd
Format: Hardcover
Pub. Date: 1999-03-01
Publisher(s): SPRINGER VERLAG INC
List Price: $64.14

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Summary

Combustion is an old technology, which at present provides about 90% of our worldwide energy support. Combustion research in the past used fluid mechanics with global heat release by chemical reactions described with thermodynamics, assuming infinitely fast reactions. This approach was useful for stationary combustion processes, but it is not sufficient for transient processes like ignition and quenching or for pollutant formation. Yet pollutant formation during combustion of fossil fuels is a central topic and will continue to be so in future. This book provides a detailed and rigorous treatment of the coupling of chemical reactions and fluid flow. Also, combustion-specific topics of chemistry and fluid mechanics are considered, and tools described for the simulation of combustion processes. For the 2nd edition, the parts dealing with experiments, spray combustion, and soot were thoroughly revised.

Table of Contents

Introduction, Fundamental Definitions and Phenomena
1(9)
Introduction
1(1)
Some Fundamental Definitions
1(3)
Basic Flame Types
4(4)
Exercises
8(1)
Experimental Investigation of Flames
9(14)
Velocity Measurements
10(1)
Density Measurement
11(1)
Concentration Measurements
12(6)
Temperature Measurements
18(2)
Pressure Measurements
20(1)
Measurement of Particle Sizes
20(1)
Simultaneous Diagnostics
21(1)
Exercises
22(1)
Mathematical Description of Premixed Laminar Flat Flames
23(10)
Conservation Equations for Laminar Flat Premixed Flames
23(4)
Heat and Mass Transport
27(1)
The Description of a Laminar Premixed Flat Flame Front
27(5)
Exercises
32(1)
Thermodynamics of Combustion Processes
33(16)
The First Law of Thermodynamics
33(2)
Standard Enthalpies of Formation
35(2)
Heat Capacities
37(1)
The Second Law of Thermodynamics
38(1)
The Third Law of Thermodynamics
39(1)
Equilibrium Criteria and Thermodynamic Variables
40(1)
Equilibrium in Gas Mixtures; Chemical Potential
41(2)
Determination of Equilibrium Compositions in Gases
43(2)
Determination of Adiabatic Flame Temperatures
45(1)
Tabulation of Thermodynamic Data
46(2)
Exercises
48(1)
Transport Phenomena
49(16)
A Simple Physical Model of the Transport Processes
49(3)
Heat Conduction in Gases
52(2)
Viscosity of Gases
54(2)
Diffusion in Gases
56(2)
Thermal Diffusion, Dufour Effect, and Pressure Diffusion
58(1)
Comparison with Experiments
59(4)
Exercises
63(2)
Chemical Kinetics
65(20)
Rate Laws and Reaction Orders
65(2)
Relation of Forward and Reverse Reactions
67(1)
Elementary Reactions, Reaction Molecularity
67(7)
Experimental Investigation of Elementary Reactions
74(1)
Temperature Dependence of Rate Coefficients
75(1)
Pressure Dependence of Rate Coefficients
76(4)
Surface Reactions
80(4)
Exercises
84(1)
Reaction Mechanisms
85(26)
Characteristics of Reaction Mechanisms
85(6)
Quasi-Steady States
86(2)
Partial Equilibrium
88(3)
Analysis of Reaction Mechanisms
91(10)
Sensitivity Analysis
91(4)
Reaction Flow Analysis
95(2)
Eigenvalue Analyses of Chemical Reaction Systems
97(4)
Stiffness of Ordinary Differential Equation Systems
101(1)
Simplification of Reaction Mechanisms
101(6)
Radical Chain Reactions
107(2)
Exercises
109(2)
Laminar Premixed Flames
111(16)
Zeldovich's Analysis of Flame Propagation
111(2)
Numerical Solution of the Conservation Equations
113(6)
Spatial Discretization
113(2)
Initial Values, Boundary Conditions, Stationary Solution
115(1)
Explicit Solution Methods
116(1)
Implicit Solution Methods
117(1)
Semi-implicit Solution of Partial Differential Equations
118(1)
Implicit Solution of Partial Differential Equations
118(1)
Flame Structures
119(3)
Flame Velocities
122(2)
Sensitivity Analysis
124(1)
Exercises
125(2)
Laminar Nonpremixed Flames
127(10)
Counterflow Nonpremixed Flames
127(4)
Laminar Jet Nonpremixed Flames
131(2)
Nonpremixed Flames With Fast Chemistry
133(3)
Exercises
136(1)
Ignition Processes
137(16)
Semenov's Analysis of Thermal Explosions
138(1)
Frank-Kamenetskii's Analysis of Thermal Explosions
139(2)
Autoignition: Ignition Limits
141(3)
Autoignition: Ignition-Delay Time
144(1)
Induced Ignition, Minimum Ignition Energies
145(4)
Spark Ignition
149(1)
Detonations
150(2)
Exercises
152(1)
The Navier-Stokes-Equations for Three-Dimensional Reacting Flows
153(10)
The Conservation Equations
153(4)
Overall Mass Conservation
154(1)
Species Mass Conservation
155(1)
Momentum Conservation
155(1)
Energy Conservation
156(1)
The Empirical Laws
157(2)
Newton's Law
157(1)
Fourier's Law
158(1)
Fick's Law and Thermal Diffusion
158(1)
Calculation of the Transport Coefficients from Molecular Parameters
159(1)
Appendix: Some Definitions and Laws from Vector- and Tensor-Analysis
159(2)
Exercises
161(2)
Turbulent Reacting Flows
163(24)
Some Fundamental Phenomena
163(2)
Direct Numerical Simulation
165(2)
Concepts for Turbulence Modeling: Probability Density Functions (PDFs)
167(1)
Concepts for Turbulence Modeling: Time- and Favre-Averaging
168(2)
Averaged Conservation Equations
170(2)
Turbulence Models
172(4)
Mean Reaction Rates
176(6)
Eddy-Break-Up Models
182(1)
Large-Eddy Simulation (LES)
182(1)
Turbulent Scales
182(2)
Exercises
184(3)
Turbulent Nonpremixed Flames
187(14)
Nonpremixed Flames with Equilibrium Chemistry
188(3)
Finite-Rate Chemistry in Nonpremixed Flames
191(4)
Flame Extinction
195(3)
PDF-Simulations of Turbulent Non-Premixed Flames
198(2)
Exercises
200(1)
Turbulent Premixed Flames
201(12)
Classification of Turbulent Premixed Flames
201(3)
Flamelet Models
204(2)
Turbulent Flame Velocity
206(2)
Flame Extinction
208(2)
Other Models of Turbulent Premixed Combustion
210(1)
Exercises
211(2)
Combustion of Liquid and Solid Fuels
213(14)
Droplet and Spray Combustion
213(11)
Combustion of Single Droplets
214(4)
Combustion of Sprays
218(6)
Coal Combustion
224(3)
Low-Temperature Oxidation, Engine Knock
227(10)
Fundamental Phenomena
227(3)
High-Temperature Oxidation
230(1)
Low-Temperature Oxidation
231(4)
Knock Damages
235(1)
Exercises
236(1)
Formation of Nitric Oxides
237(20)
Thermal NO (Zeldovich-NO)
237(3)
Prompt NO (Fenimore-NO)
240(3)
NO Generated via Nitrous Oxide
243(1)
Conversion of Fuel Nitrogen into NO
243(6)
No Reduction by Combustion Modifications
249(2)
Catalytic Combustion
251(2)
NO-Reduction by Post-Combustion Processes
253(4)
Formation of Hydrocarbons and Soot
257(16)
Unburnt Hydrocarbons
257(3)
Flame Extinction Due to Strain
258(1)
Flame Extinction at Walls and in Gaps
258(2)
Formation of Polycyclic Aromatic Hydrocarbons (PAH)
260(2)
The Phenomenology of Soot Formation
262(4)
Modelling and Simulation of Soot Formation
266(7)
References
273(16)
Index
289

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