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1.1 Stability Constants - Early Work |
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1.3 Historical Evolution of Computational Methods |
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2 Equilibrium Constants, Protonation Constants, Formation Constants |
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2.1 Concentration Constants and Activity Constants |
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2.2 Conventions Employed for Expressing Equilibrium Constants |
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2.3 Equilibrium Constants and Stability Constants for Ca(II)-EDTA |
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2.4 Species Distribution Curves |
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3 Experimental Methods for Measuring Equilibrium Constants |
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3.2 Potentiometric pH Measurements |
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4 Experimental Procedure for Potentiometric p[H] Measurement of Metal Complex Equilibria |
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4.3 Calibration of the Potentiometric Apparatus |
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4.4 The Experimental Runs |
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4.5 Computation of Stability Constants |
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5 Common Errors and Their Elimination or Minimization |
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5.2 Calibration and Electrode Care |
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5.4 Equilibrium Measurements |
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5.6 Selection of the Model |
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6 Examples of Stability Constant Determinations |
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6.1 Iminodiacetic Acid (IDA) |
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Checking the electrode system |
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Final calculation for IDA protonation constants |
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6.4 Procedure for C-Bistren |
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Computation of Cu(II)/CBT stability constants |
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6.5 Determination of Stability Constants in the Presence of Competing Ligands |
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7 Macroscopic and Microscopic Constants |
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7.1 Some Definitions and Concepts |
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7.2 Ionization of Tyrosine |
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7.3 Macroscopic and Microscopic Protonation Equilibria of DOPA |
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7.4 General Comments and Conclusions |
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8 Determination of Stability Constants and Species Concentration of Complex Systems |
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8.1 A Mixed-Ligand Binuclear Dioxygen System |
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8.3 Complex Multicomponent Systems |
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8.4 Equilibrium with Solid Phases |
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8.5 Equilibrium Involving Hydrolytic Species |
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8.6 Species Distributions of Hydroxo and Fluoro Complexes of Al(III) |
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9 Critical Stability Constants and Their Selection |
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Essential experimental control |
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Selection of a constant from a number of reported values |
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Reliability of investigator |
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9.2 Examples of Critical Data Selection |
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9.3 Need for Additional Critical Constants |
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10 Development of a Complete Critical Metal Complex Data Base |
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10.2 Linear Stability Constant Correlations |
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10.3 Estimation of Stability Constants Not Measured Experimentally |
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10.4 Metal Speciation in Sea Water With and Without Added Ligands |
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Scientific and Technical Fields Requiring Stability Data |
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