Organic Chemistry

by ; ; ;
Edition: 1st
Format: Paperback
Pub. Date: 2000-08-31
Publisher(s): Oxford University Press
List Price: $159.72

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Summary

This new and innovative text helps students develop a deeper understanding of organic chemistry. It treats the subject as a coherent whole, complete with numerous logical connections, consequences, and an underlying structure and "language." Employing an approach based on mechanism and reaction type, the book empasizes understanding ideas rather than merely memorizing facts. It shows students how to realistically draw molecules and mechanisms to reveal the fundamental chemistry. Using a fresh, accessible writing style as well as examples from everyday life, the authors explain the basics of organic chemistry carefully and thoroughly. A special focus on mechanism, orbitals, and stereochemistry helps students gain a solid comprehension of important factors common to all reactions. The book's innovative design enhances clarity and instruction with boxes that separate summary information and other material from the main text; a variety of colors that draw attention to items such as atoms, molecules, and orbitals; and figures that are drawn in red with significant parts emphasized in black. Early chapters feature carbonyl group reactions, and later chapters systematically develop the chemistry through discussions of spectroscopy, stereochemistry, and chemical reactions. Each chapter opens with a "Connections" box, divided into three columns: · Building on: Details material from previous chapters that relate to the current chapter · Arriving at: Provides a guide to the content of the chapter · Looking forward to: Previews later chapters, which develop and expand the current material

Table of Contents

What is organic chemistry?
1(18)
Organic chemistry and this book
15(4)
Organic structures
19(28)
Determining organic structures
47(34)
Structure of molecules
81(32)
Organic reactions
113(22)
Nucleophilic addition to the carbonyl group
135(16)
Delocalization and conjugation
151(30)
Acidity, basicity, and pKa
181(28)
Using organometallic reagents to make C-C bonds
209(18)
Conjugate addition
227(16)
Proton nuclear magnetic resonance
243(36)
Nucleophilic substitution at the carbonyl (C=O) group
279(26)
Equilibria, rates, and mechanisms: summary of mechanistic principles
305(34)
Nucleophilic substitution at C=O with loss of carbonyl oxygen
339(22)
Review of spectroscopic methods
361(20)
Stereochemistry
381(26)
Nucleophilic substitution at saturated carbon
407(40)
Conformational analysis
447(30)
Elimination reactions
477(26)
Electrophilic addition to alkenes
503(20)
Formation and reactions of enols and enolates
523(24)
Electrophilic aromatic substitution
547(34)
Electrophilic alkenes
581(34)
Chemoselectivity: selective reactions and protection
615(28)
Synthesis in action
643(20)
Alkylation of enolates
663(26)
Reactions of enolates with aldehydes and ketones: the aldol reaction
689(34)
Acylation at carbon
723(26)
Conjugate addition of enolates
749(22)
Retrosynthetic analysis
771(32)
Controlling the geometry of double bonds
803(20)
Determination of stereochemistry by spectroscopic methods
823(28)
Stereoselective reactions of cyclic compounds
851(30)
Diastereoselectivity
881(24)
Pericyclic reactions 1: cycloadditions
905(38)
Pericyclic reactions 2: sigmatropic and electrocyclic reactions
943(26)
Rearrangements
969(34)
Fragmentation
1003(16)
Radical reactions
1019(34)
Synthesis and reactions of carbenes
1053(26)
Determining reaction mechanisms
1079(42)
Saturated heterocycles and stereoelectronics
1121(26)
Aromatic heterocycles 1: structures and reactions
1147(38)
Aromatic heterocycles 2: synthesis
1185(34)
Asymmetric synthesis
1219(28)
Organo-main-group chemistry I: sulfur
1247(30)
Organo-main-group chemistry II: boron, silicon, and tin
1277(34)
Organometallic chemistry
1311(34)
The chemistry of life
1345(36)
Mechanisms in biological chemistry
1381(32)
Natural products
1413(38)
Polymerization
1451(30)
Organic chemistry today
1481(10)
Index 1491

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